Product ID:ID 775-7325, 81-67-1, USDA BLUE TMP
MSDS Date:05/03/1990
FSC:8010
NIIN:01-273-3764
MSDS Number: BJNSK

SOUTHERN COATINGS

SUMTER, SC 29150
US

Emergency Phone: 803-775-6351

Info Phone: 803-775-6351

Cage: 6M840

SOUTHERN COATINGS

160 SUMTER, SC 29150 US

Telephone: 803-775-6351

Cage: 6M840

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

MINERAL SPIRITS (VAPOR PRESSURE 2 MMHG @ 20C)

CAS: 64742-88-7

OSHA PEL 100 PPM/525 MG/CU.M.

ACGIH TLV: 100 PPM/525 MG/CU.M.

VOC. 4.86 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY

RTECS: 9999999VO

VOC. 19.21 LB/GAL SOLIDS 2305 G/L SOLIDS CALCULATED

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED
PROLONGED/REPEATED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS
W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL
OR FATAL. NOTE TO PHYSICIAN: DIRECT TREATMENT FOR OVEREXPOSURE AT
CONTROL OF SYMPTOMS/CLINICAL CONDITIONS.
Explanation of Carcinogenicity:AT THE TLV THE TIO2 MANUFACTURER
CONCLUDES THAT THERE IS NO SIGNIFICANT HAZARD FOR MAN. SEE FILE FOR
MORE INFORMATION.
Effects of Overexposure:SWALLOW:GASTROINTESTINAL IRRIT, NAUSEA &
VOMITING. ASPIRATION INTO LUNGS MAY CAUSE CHEM PNEUMONITIS, CAN BE
FATAL. INHALE:NOSE OR THROAT IRRIT. HIGH CONCENTRATE MAY CAUSE
ACUTE CENTRAL NERVOUS SYSTEM DEPRESSION, CHARACTERIZED
BY;HEADACHE, DIZZINESS, NAUSEA & CONFUSION. EYES: IRRIT. SKIN: MAY
CAUSE DEFATTING & IRRIT.

First Aid:SWALLOW: DO NOT INDUCE VOMITING. CALL POISON CONTROL
CENTER/EMERGENCY ROOM/PHYSICIAN IMMED. INHALED: REMOVE TO FRESH AIR
IMMED. IF BREATHING STOPPED, GIVE CPR. KEEP WARM & QUIET. GET MED
ATTN IMMED. E YES: FLUSH W/LARGE AMOUNTS OF WATER, LIFTING LIDS FOR
AT LEAST 15 MINUTES, GET MED ATTN. SKIN: REMOVE CONTAMINATED
CLOTHING, WASH AREAS W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IF
IRRIT PERSIST.

Flash Point:>102F/>39C
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS FOR FLAMMABLE
LIQUID FIRES. POLYMER FOAM IS PREFERRED FOR LARGE FIRES.
Fire Fighting Procedures:FIREFIGHTER SHOULD WEAR SCBA. USE WATER TO
COOL EXPOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP/AUTO-IGNITE/EXPLOSION FROM EXTREME HEAT. FOG NOZZLES
PREFERABLE.
Unusual Fire/Explosion Hazard:OVEREXPOS TO DECOMP PROD MAY CAUSE HEALTH
HAZARD. SYMP MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. KEEP
CONTAINERS TIGHTLY CLOSED, MAY EXPLODE FROM HEAT/FLAME.

Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM ALL IGNITE SOURCES.
DIKE & CONTAIN SPILL W/INERT MATERIAL(SAND,EARTH). TRANSFER LIQ TO
COVERED METAL CONTAIN FOR RECOVERY/DISPOSAL OR REMOVE W/INERT
ABSORB. USE ONLY NON-SPA RK TOOLS.PREVENT CONTAM OF
SEWER/STREAMS/GROUNDWTR

Handling and Storage Precautions:DO NOT STORE ABOVE 95 DEGREES F. STORE
LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH
USE. EMPTY CONTAINERS MUST NOT BE WASHED AND RE-USED FOR ANY
PURPOSE. CONTAINERS SHOULD BE GROUNDED & BONDED TO THE RECEIVING
CONTAINER. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINERS. *

Respiratory Protection:WELL VENTED AREA MAY NOT REQUIRE USE OF RSPRTR.
RESTRICTED VENT:CHEM CARTRIDGE RSPRTR MAY BE REQUIRED. SPRAY:USE
MECH PREFILTER. CONFINED AREA:USE AIR SUPPLIED RSPRTR.IF TLV EXCEED
USE PROPERLY FITTED RSPRTR WITH PROTECTION FACTOR
Ventilation:GEN DILUTE & LOCAL EXHAUST VENT IN SUFF VOL/PATTERN TO
MAINTAIN CONCENTR OF HAZARD SUBSTANCE BELOW LOWEST EXPOS LIMIT
Protective Gloves:SOLVENT IMPERMEABLE
Eye Protection:WEAR SAFETY SPECTACLES.
Other Protective Equipment:NOT LIKELY TO BE NEEDED.
Supplemental Safety and Health
* NEVER USE PRESSURE TO EMPTY. DRUM IS NOT A PRESSURE VESSEL. IT IS
HIGHLY UNLIKELY THESE TLV LIMITS WILL BE EXCEEDED WITH OUTDOOR
APPLICATION OF THIS PRODUCT.

Boiling Pt:B.P. Text:280 TO 390F
Vapor Density:> THAN AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:74

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS AND
FLAME.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL LAWS. IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED A HAZARDOUS
WASTE BASED ON ITS IGNITABILITY CHARACTERISTIC. THE PROPER RCRA
CLASSIFICATION WOULD BE D001.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.